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No Password Required! Arunachalam Tamil Full Hd Movie Free Download 3gp. Mp4 Mp3. 1 movie climax rhyme mp3 downloadinstmank - download (mirror #1) 1 movie climax rhyme .2,3-Dihydro-3-vinylisoxazolones are intermediates in the synthesis of antifungal compounds and have been synthesized in the past using a Friedel-Crafts or Diels-Alder cyclization. In European patent applications EP 95535 and EP 95337, substituted 1-isoxazolones were prepared using a cyclization of an aldehyde or ketone with an isoxazolone. In European patent application 95535, the 1-isoxazolones were dihydroxylated and in European patent application 95337 the 1-isoxazolones were nitrated.
In European patent application 796808, 1-isoxazolones are formed by reacting aryl aldehydes with a diazo compound and a nucleophile. In the present invention, a diazo compound is reacted with a 1-isoxazolone under very mild conditions to form a 3-vinylisoxazolone intermediate in a one-step procedure.
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